Electron Reservoir Activity of High-Nuclearity Transition Metal Carbonyl Clusters
نویسندگان
چکیده
منابع مشابه
Transition metal-catalyzed reduction of carbonyl compounds
.................................................................................................................... iii List of publications ..................................................................................................... v Abbreviations ............................................................................................................. ix
متن کاملTransition metal carbonyl oestrogen receptor assay
Hormonal steroids, such as 17 -estradio1 derivatives, labelled with organometallic moieties have been synthesized and tested as markers for hormone receptor assay. Among the organometallic labels used were : Cr(C0) and Cr(C0)9(CS) which5can be attached to the arene A ring of the sterid ; Co9(C06 and Mo(rì -CH)9(C0)4 which can be bonded to acetylenic groups introduced at the 17c-p6sWton o the fl...
متن کاملPropentdyopent: the scaffold of a heme metabolite as an electron reservoir in transition metal complexes.
The dipyrrin-1,9-dione scaffold of heme metabolite propendyopent coordinates late transition metals (Co, Ni, Cu, and Zn) forming homoleptic, pseudo-tetrahedral complexes. Electrochemical and spectroscopic studies reveal that the monoanionic, bidentate ligands behave as electron reservoirs as the complexes reversibly host one or two ligand-based radicals.
متن کاملA high-nuclearity metal-cyanide cluster [Mo6Cu14] with photomagnetic properties.
A high-nuclearity metal-cyanide cluster [Mo6Cu14] has been prepared and its photomagnetic properties investigated. The photoswitchable magnetic phenomenon observed is thermally reversible (T≈ 230 K). In the field of photomagnetism, [Mo6Cu14] represents a unique example of a nanocage and the highest nuclearity observed so far.
متن کاملMagnetic anisotropy of deposited transition metal clusters
We present results of magnetic torque calculations using the fully relativistic spin-polarized Korringa-Kohn-Rostoker approach applied to small Co and Fe clusters deposited on the Pt(111) surface. From the magnetic torque one can derive amongst others the magnetic anisotropy energy (MAE). It was found that this approach is numerically much more stable and also computationally less demanding tha...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Portugaliae Electrochimica Acta
سال: 2011
ISSN: 1647-1571
DOI: 10.4152/pea.201105309